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rhodium hexafluoride : ウィキペディア英語版
rhodium hexafluoride

Rhodium hexafluoride, also rhodium(VI) fluoride, (RhF6) is the inorganic compound of rhodium and fluorine. A black volatile solid,〔 it is highly reactive material, and a rare example of rhodium(VI) compound.
== Synthesis, structure, properties==
Rhodium hexafluoride is prepared by reaction of rhodium metal with an excess of elemental fluorine:〔
:Rh + 3 F2 → RhF6
The RhF6 molecule has octahedral molecular geometry. Consistent with its d3 configuration, the six Rh–F bond lengths are equivalent, being 1.824 Å.〔 It crystallises in an orthorhombic space group ''Pnma'' with lattice parameters of ''a'' = 9.323 Å, ''b'' = 8.474 Å, and ''c'' = 4.910 Å.
Like some other metal fluorides, RhF6 is highly oxidising. It attacks even glass even in the absence of water.〔 It can even react with elemental oxygen.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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